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- W2077693883 abstract "High molecular weight polyisobutylene shows a T2S relaxation spectrum typical of a highly crosslinked or entangled network. In conformity with theory the reduction of molecular weight by radiation shows a reduction in the T2S (network) fraction (1−ƒ), and an increase in the T2L (non-network) fraction (ƒ), until the network fraction disappears. The average molecular weight Me between entangled units at 144°C is 2 × 104; it varies only slightly with temperature, and not significantly with overall molecular weight. The quantity T2LM−0.5n is constant at a fixed temperature T. Its variation with T is similar to that of viscosity. The variation of T2L with molecular weight of molecules in the non-network fraction and of T2S with Me in the network fraction do not agree with the theory for the two fractions considered separately. This is ascribable in part to their mutual interaction." @default.
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- W2077693883 date "1982-01-01" @default.
- W2077693883 modified "2023-10-16" @default.
- W2077693883 title "NMR measurement of entanglement density in irradiated polyisobutylene" @default.
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- W2077693883 doi "https://doi.org/10.1016/0146-5724(82)90021-8" @default.
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