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- W2077694294 abstract "Synthetic routes for the preparation of halogenated diphenyl ethers and dibenzofurans are reviewed, and isomers reported in the literature are listed. In addition, the routes preferred for the synthesis of specific chlorinated isomers - especially from the point of view of an unambiguous structural assignment - are discussed in detail. The route recommended for chlorinated diphenyl ethers is the coupling of biaryliodonium salts with phenols, and for chlorinated dibenzofurans the palladium acetate-promoted cyclization of diphenyl ethers. Chlorinated isomers of diphenyl ethers and dibenzofurans which are available via these routes are listed. Furthermore, the synthesis of a new octachlorodiphenyliodonium salt and its coupling with three different chlorophenols are described, and the cyclization of an octachlorodiphenyl ether to octachlorodibenzofuran is shown." @default.
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- W2077694294 date "1981-01-01" @default.
- W2077694294 modified "2023-09-27" @default.
- W2077694294 title "Synthesis of halogenated diphenyl ethers and dibenzofurans - A discussion of specific isomers available" @default.
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- W2077694294 doi "https://doi.org/10.1016/0045-6535(81)90233-2" @default.
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