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- W2077698857 startingPage "10959" @default.
- W2077698857 abstract "A reversible transformation has been observed in the ${mathrm{K}}_{mathit{x}}$${mathrm{C}}_{60}$ system, for 0x3, which is characterized by a redistribution of K ions within the fcc ${mathrm{C}}_{60}$ lattice. Below ensuremath{sim}150 ifmmode^circelsetextdegreefi{}C the tetrahedral and octahedral sites are occupied in the ratio found for ${mathrm{K}}_{3}$${mathrm{C}}_{60}$, 2 to 1, and C 1s photoemission spectra indicate phase separation into ensuremath{alpha}-${mathrm{C}}_{60}$ and ${mathrm{K}}_{3}$${mathrm{C}}_{60}$. Above ensuremath{sim}150 ifmmode^circelsetextdegreefi{}C, only octahedral sites are occupied for x1, which results in ${mathrm{KC}}_{60}$ in the NaCl structure. Tetrahedral sites are then successively filled for x>1, reflecting ${mathrm{K}}_{3}$${mathrm{C}}_{60}$ formation and coexistence with ${mathrm{KC}}_{60}$. These results suggest a eutectoid reaction with ${mathrm{KC}}_{60}$ transforming into ensuremath{alpha}-${mathrm{C}}_{60}$ plus ${mathrm{K}}_{3}$${mathrm{C}}_{60}$." @default.
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- W2077698857 date "1993-04-15" @default.
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- W2077698857 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>KC</mml:mi></mml:mrow><mml:mrow><mml:mn>60</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>fulleride phase formation: An x-ray photoemission study" @default.
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- W2077698857 doi "https://doi.org/10.1103/physrevb.47.10959" @default.
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