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• W2077707470 abstract "Successive phase transitions of K 2 ZnCl 4 have been studied by Raman scattering. The critical behaviour of the normal-incommensurate phase transition was discussed on the basis of the temperature dependence of the amplitude-mode frequency and the intensity ratio of this mode to the 49 cm -1 peak. It does not agree with the mean-field theory. At low temperatures this frequency is affected by the low-temperature phase transition. With respect to the low-temperature phase transition, a new soft mode was found in addition to a totally symmetric soft mode. Polarization characteristics of these soft modes show that the low-temperature phase has C s 4 symmetry. The temperature dependence of these soft-mode frequencies indicates that the transition temperature is 155 K. A Landau theory was applied to calculate the frequencies of the amplitude mode and the two soft modes." @default.
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• W2077707470 date "1986-11-15" @default.
• W2077707470 modified "2023-10-03" @default.
• W2077707470 title "Raman-Scattering Study of Successive Phase Transitions in K₂ZnCl₄" @default.
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• W2077707470 doi "https://doi.org/10.1143/jpsj.55.3903" @default.
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