Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077709011> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2077709011 endingPage "2054" @default.
- W2077709011 startingPage "2049" @default.
- W2077709011 abstract "Thermolysis of 1,1,2,2-tetrakis(trimethylsilyl)dispiro[3,3‘,4,4‘-biadamantane-1,2-disilacyclobutane] (6) yields (75%) the stable 1,1,2,2,3,3-hexakis(trimethylsilyl)spiro[(4,4‘-adamantane)-trisilacyclobutane] (5). The structure of 5 was determined by X-ray analysis. Thermolysis of 6 probably proceeds via the simultaneous formation of two transients, bis(trimethylsilyl)adamantylidenesilene (7) and tetrakis(trimethylsilyl)disilene (11), which then undergo cycloaddition to form 5. Photolysis of 5 leads to a [2+2] cycloreversion reaction producing the silene 7 and the disilene 11. This is the first demonstration that a silene and a disilene can be generated simultaneously from a single precursor." @default.
- W2077709011 created "2016-06-24" @default.
- W2077709011 creator A5020331331 @default.
- W2077709011 creator A5031616189 @default.
- W2077709011 creator A5048752694 @default.
- W2077709011 creator A5075148080 @default.
- W2077709011 date "2002-04-18" @default.
- W2077709011 modified "2023-09-29" @default.
- W2077709011 title "Thermal Transformation of a 1,2-Disilacyclobutane to a Trisilacyclobutane" @default.
- W2077709011 cites W1576206570 @default.
- W2077709011 cites W1975481764 @default.
- W2077709011 cites W2005575251 @default.
- W2077709011 cites W2010624074 @default.
- W2077709011 cites W2012074067 @default.
- W2077709011 cites W2013952441 @default.
- W2077709011 cites W2040916013 @default.
- W2077709011 cites W2066060574 @default.
- W2077709011 cites W2092449070 @default.
- W2077709011 cites W2134161223 @default.
- W2077709011 cites W2148066840 @default.
- W2077709011 cites W2154344009 @default.
- W2077709011 cites W2340406231 @default.
- W2077709011 cites W2949663538 @default.
- W2077709011 cites W3005171039 @default.
- W2077709011 cites W4206296580 @default.
- W2077709011 cites W4236017535 @default.
- W2077709011 doi "https://doi.org/10.1021/om0107690" @default.
- W2077709011 hasPublicationYear "2002" @default.
- W2077709011 type Work @default.
- W2077709011 sameAs 2077709011 @default.
- W2077709011 citedByCount "11" @default.
- W2077709011 countsByYear W20777090112013 @default.
- W2077709011 countsByYear W20777090112014 @default.
- W2077709011 crossrefType "journal-article" @default.
- W2077709011 hasAuthorship W2077709011A5020331331 @default.
- W2077709011 hasAuthorship W2077709011A5031616189 @default.
- W2077709011 hasAuthorship W2077709011A5048752694 @default.
- W2077709011 hasAuthorship W2077709011A5075148080 @default.
- W2077709011 hasConcept C124681953 @default.
- W2077709011 hasConcept C155647269 @default.
- W2077709011 hasConcept C160434732 @default.
- W2077709011 hasConcept C161790260 @default.
- W2077709011 hasConcept C178790620 @default.
- W2077709011 hasConcept C185592680 @default.
- W2077709011 hasConcept C2777000832 @default.
- W2077709011 hasConcept C2777336512 @default.
- W2077709011 hasConcept C2779664164 @default.
- W2077709011 hasConcept C54355233 @default.
- W2077709011 hasConcept C54582936 @default.
- W2077709011 hasConcept C75473681 @default.
- W2077709011 hasConcept C86803240 @default.
- W2077709011 hasConceptScore W2077709011C124681953 @default.
- W2077709011 hasConceptScore W2077709011C155647269 @default.
- W2077709011 hasConceptScore W2077709011C160434732 @default.
- W2077709011 hasConceptScore W2077709011C161790260 @default.
- W2077709011 hasConceptScore W2077709011C178790620 @default.
- W2077709011 hasConceptScore W2077709011C185592680 @default.
- W2077709011 hasConceptScore W2077709011C2777000832 @default.
- W2077709011 hasConceptScore W2077709011C2777336512 @default.
- W2077709011 hasConceptScore W2077709011C2779664164 @default.
- W2077709011 hasConceptScore W2077709011C54355233 @default.
- W2077709011 hasConceptScore W2077709011C54582936 @default.
- W2077709011 hasConceptScore W2077709011C75473681 @default.
- W2077709011 hasConceptScore W2077709011C86803240 @default.
- W2077709011 hasIssue "10" @default.
- W2077709011 hasLocation W20777090111 @default.
- W2077709011 hasOpenAccess W2077709011 @default.
- W2077709011 hasPrimaryLocation W20777090111 @default.
- W2077709011 hasRelatedWork W1574148762 @default.
- W2077709011 hasRelatedWork W2004798939 @default.
- W2077709011 hasRelatedWork W2038198776 @default.
- W2077709011 hasRelatedWork W2038571630 @default.
- W2077709011 hasRelatedWork W2061744402 @default.
- W2077709011 hasRelatedWork W2077709011 @default.
- W2077709011 hasRelatedWork W2166992585 @default.
- W2077709011 hasRelatedWork W2950180053 @default.
- W2077709011 hasRelatedWork W2952549720 @default.
- W2077709011 hasRelatedWork W786667567 @default.
- W2077709011 hasVolume "21" @default.
- W2077709011 isParatext "false" @default.
- W2077709011 isRetracted "false" @default.
- W2077709011 magId "2077709011" @default.
- W2077709011 workType "article" @default.