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- W2077730073 abstract "Abstract BaBiO 3 has a pressure-induced phase transition at 8–10 GPa, where the lattice changes from nearly cubic to nearly tetragonal, and a new Raman band stretching mode appears. A similar change in the Raman spectrum is observed in a Sb substituted compound BaSb x Bi 1- x O 3 . These observations are considered to indicate that the separation of the valence state is accelerated by compression and Sb substitution, and that the mixed valence state, Bi 3+ and Bi 5+ , is attained in the high pressure phase of BaBiO 3 ." @default.
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- W2077730073 date "1986-05-01" @default.
- W2077730073 modified "2023-09-25" @default.
- W2077730073 title "High pressure studies on the perovskite-type compound BaBiO3" @default.
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- W2077730073 doi "https://doi.org/10.1016/0378-4363(86)90596-6" @default.
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