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- W2077761388 abstract "Lipophilic lanthanide complexes of fluorinated β-diketonate ligands were demonstrated to bind unprotected phenylalanine, leucine, and other amino acids under neutral conditions. Extraction experiments supported that these lanthanide tris(β-diketonates) formed highly coordinated 1:1 complexes with amino acids, although they were electrically neutralized. NMR and CD spectroscopic studies further suggested that the lanthanide tris(β-diketonates) bound amino acids at two points. Their extraction, transport, and chiral recognition behaviors were significantly controlled by a combination of central lanthanide cation and coordinating ligand: Chiral ytterbium complex offered good enantioselectivity in the extraction of unprotected amino acids, and the related praseodymium complex provided their efficient membrane transport. Thus, these lipophilic lanthanide tris(β-diketonates) were confirmed to be a new class of receptors for amino acids." @default.
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- W2077761388 date "1998-03-12" @default.
- W2077761388 modified "2023-10-16" @default.
- W2077761388 title "Molecular Recognition with Lanthanide(III) Tris(β-diketonate) Complexes: Extraction, Transport, and Chiral Recognition of Unprotected Amino Acids" @default.
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- W2077761388 doi "https://doi.org/10.1021/ic970103r" @default.
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