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- W2077761409 abstract "The dibromomaleimide derivative, N-(4-bromobutyl)-dibromomaleimide (dBMIB), is found to be a highly efficient coupling agent to dimerize thiol-terminated hydrophilic polymers by substituent reaction. When mono-thiol poly(ethylene oxide) (PEO45-SH) is mixed with dBMIB in an equivalent molar feed in water, a dimer of PEO45 with a maleimide unit located at the chain center, (PEO45)2MIB, is obtained quantitatively. The dBMIB is also used to dimerize thiol- terminated poly(N-(2-acryloyloxyethyl) pyrrolidone) and poly(N,N-dimethyl acrylamide). Moreover, the butylene bromide of (PEO45)2MIB is transferred into a butylene azide, which is allowed to react with alkynyl-terminated polystyrene to give a A2B miktoarm star polymer via a copper-catalyzed azide–alkyne cycloaddition coupling reaction." @default.
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- W2077761409 date "2012-11-29" @default.
- W2077761409 modified "2023-09-27" @default.
- W2077761409 title "Dibromomaleimide Derivative as an Efficient Polymer Coupling Agent for Building Topological Polymers" @default.
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