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• W2077766118 abstract "Proton spin-lattice relaxation time T1 in the plastic phase of 2,2-dimethylpropane (neopentane) was measured at 10 MHz up to 170 MPa between 192.7 and 308.2 K. T1 near the melting point is determined by self-diffusion. The enthalpy and volume of activation of this motion suggest that self-diffusion occurs through a single vacancy mechanism. The correlation time of self-diffusion at the melting point (Tf) is (3.2±0.5)×10−7 s irrespective of external pressure. The diffusion rate is a function only of Tf⁄T, i.e. the law of corresponding states holds. The feature of activation properties of self-diffusion is strongly correlated with the melting phenomenon. The melting curve of the phase diagram was also determined and a possibility of existence of another plastic phase was found above 40 MPa." @default.
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• W2077766118 date "1983-07-01" @default.
• W2077766118 modified "2023-09-26" @default.
• W2077766118 title "Self-diffusion and Melting in the Plastic Phases of Neopentane as Studied by NMR Relaxation at High Pressures" @default.
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• W2077766118 doi "https://doi.org/10.1246/bcsj.56.2101" @default.
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