Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077771837> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2077771837 abstract "Abstract The γ-ray initiated radical telomerization of ethylene by bromodecane has been used as the model reaction in the study of the mechanism and kinetics of non-linear structure formation in low density (high pressure) polyethylene (HPPE). The identification of the reaction products showed a 1,5-rearrangement to take place of the intermediate alkyl radicals which is accompanied by a hydrogen atom migration. This type of isomerization explains the presence of the short butyl and ethyl branches in the PE molecules. The competing kinetics method has been used to find the isometrization constants in the 30–150°C range for which the parameters of the Arrhenius equation have been determined. The findings permitted the calculation of the branching intensity for various process technology parameters (temperature and pressure)." @default.
- W2077771837 created "2016-06-24" @default.
- W2077771837 creator A5000363749 @default.
- W2077771837 creator A5000877192 @default.
- W2077771837 creator A5012213703 @default.
- W2077771837 date "1978-01-01" @default.
- W2077771837 modified "2023-09-25" @default.
- W2077771837 title "The mechanism and the kinetics of polyethylene branching studied on a model system" @default.
- W2077771837 cites W1987252741 @default.
- W2077771837 cites W2006457861 @default.
- W2077771837 cites W2086704271 @default.
- W2077771837 cites W2086951452 @default.
- W2077771837 cites W2316268457 @default.
- W2077771837 cites W2323010187 @default.
- W2077771837 doi "https://doi.org/10.1016/0032-3950(78)90431-8" @default.
- W2077771837 hasPublicationYear "1978" @default.
- W2077771837 type Work @default.
- W2077771837 sameAs 2077771837 @default.
- W2077771837 citedByCount "2" @default.
- W2077771837 crossrefType "journal-article" @default.
- W2077771837 hasAuthorship W2077771837A5000363749 @default.
- W2077771837 hasAuthorship W2077771837A5000877192 @default.
- W2077771837 hasAuthorship W2077771837A5012213703 @default.
- W2077771837 hasConcept C121332964 @default.
- W2077771837 hasConcept C126661725 @default.
- W2077771837 hasConcept C147789679 @default.
- W2077771837 hasConcept C148898269 @default.
- W2077771837 hasConcept C161790260 @default.
- W2077771837 hasConcept C178790620 @default.
- W2077771837 hasConcept C185592680 @default.
- W2077771837 hasConcept C188027245 @default.
- W2077771837 hasConcept C206175624 @default.
- W2077771837 hasConcept C2776640939 @default.
- W2077771837 hasConcept C2778597550 @default.
- W2077771837 hasConcept C2779751980 @default.
- W2077771837 hasConcept C2780263894 @default.
- W2077771837 hasConcept C36663273 @default.
- W2077771837 hasConcept C62520636 @default.
- W2077771837 hasConcept C75473681 @default.
- W2077771837 hasConcept C86183883 @default.
- W2077771837 hasConcept C95121573 @default.
- W2077771837 hasConcept C97355855 @default.
- W2077771837 hasConceptScore W2077771837C121332964 @default.
- W2077771837 hasConceptScore W2077771837C126661725 @default.
- W2077771837 hasConceptScore W2077771837C147789679 @default.
- W2077771837 hasConceptScore W2077771837C148898269 @default.
- W2077771837 hasConceptScore W2077771837C161790260 @default.
- W2077771837 hasConceptScore W2077771837C178790620 @default.
- W2077771837 hasConceptScore W2077771837C185592680 @default.
- W2077771837 hasConceptScore W2077771837C188027245 @default.
- W2077771837 hasConceptScore W2077771837C206175624 @default.
- W2077771837 hasConceptScore W2077771837C2776640939 @default.
- W2077771837 hasConceptScore W2077771837C2778597550 @default.
- W2077771837 hasConceptScore W2077771837C2779751980 @default.
- W2077771837 hasConceptScore W2077771837C2780263894 @default.
- W2077771837 hasConceptScore W2077771837C36663273 @default.
- W2077771837 hasConceptScore W2077771837C62520636 @default.
- W2077771837 hasConceptScore W2077771837C75473681 @default.
- W2077771837 hasConceptScore W2077771837C86183883 @default.
- W2077771837 hasConceptScore W2077771837C95121573 @default.
- W2077771837 hasConceptScore W2077771837C97355855 @default.
- W2077771837 hasLocation W20777718371 @default.
- W2077771837 hasOpenAccess W2077771837 @default.
- W2077771837 hasPrimaryLocation W20777718371 @default.
- W2077771837 hasRelatedWork W1514571358 @default.
- W2077771837 hasRelatedWork W1970418595 @default.
- W2077771837 hasRelatedWork W1972366984 @default.
- W2077771837 hasRelatedWork W1975090789 @default.
- W2077771837 hasRelatedWork W1980725070 @default.
- W2077771837 hasRelatedWork W2003076703 @default.
- W2077771837 hasRelatedWork W2010311200 @default.
- W2077771837 hasRelatedWork W2010569460 @default.
- W2077771837 hasRelatedWork W2016872215 @default.
- W2077771837 hasRelatedWork W2027574810 @default.
- W2077771837 hasRelatedWork W2033613375 @default.
- W2077771837 hasRelatedWork W2035979036 @default.
- W2077771837 hasRelatedWork W2039306943 @default.
- W2077771837 hasRelatedWork W2061035476 @default.
- W2077771837 hasRelatedWork W2062172481 @default.
- W2077771837 hasRelatedWork W2070436362 @default.
- W2077771837 hasRelatedWork W2075257472 @default.
- W2077771837 hasRelatedWork W2077291853 @default.
- W2077771837 hasRelatedWork W2086230156 @default.
- W2077771837 hasRelatedWork W2800406274 @default.
- W2077771837 isParatext "false" @default.
- W2077771837 isRetracted "false" @default.
- W2077771837 magId "2077771837" @default.
- W2077771837 workType "article" @default.