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• W2077772480 abstract "Adaptable DNA Analogs The defining feature of DNA as a genetic blueprint is its capacity for self-replication. In the cell, however, the replication process requires the assistance of multiple elaborate enzymes. How then at the origin of life could DNA or its precursor replicate before enzymes were present? Ura et al. (p. 73 , published online 11 June) have achieved the long-sought goal of preparing a synthetic DNA analog that can dynamically adapt its sequence in free solution. Their analog (as yet only studied in relatively short, 20-unit oligomers) replaces DNA's sugar and phosphate backbone by a peptide strand in which cysteines reversibly bind the conventional DNA bases through thioester tethers. These strands can pair with complementary sequences of true DNA and furthermore swap one tethered base for another if different DNA templating strands are added to the solution in succession." @default.
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• W2077772480 date "2009-07-03" @default.
• W2077772480 modified "2023-10-03" @default.
• W2077772480 title "Self-Assembling Sequence-Adaptive Peptide Nucleic Acids" @default.
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• W2077772480 doi "https://doi.org/10.1126/science.1174577" @default.
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