Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077772916> ?p ?o ?g. }
- W2077772916 abstract "A new family of luminescent platinum(II) acetylide complexes and polymers were formed by the copper(I) catalyzed reaction of cis-[PtCl2(PR3)2] (R=C6H5–p-CH3) with appropriate acetylide ligands. The reaction of metal precursors with 2.5 equivalents of monoterminal acetylide ligands provided metal complexes trans-[Pt(p-tolyl3P)2(C≡C-R)2] (R=C6H4-p-NO2 (1) C6H4 -p-CH3 (2)), and equimolar amounts of diterminal ligand and metal chloride precursor, under reflux, afforded the metal poly-yne polymers [-Pt(p-tolyl3P)2C≡C–R–C≡C–]n, (R=biphenyl and 2,5-dioctyloxybenzene). Characterization of the newly developed polymer and metal complexes was accomplished by FT-IR, multinuclear NMR (1H, 31P, 13C) and mass spectrometry, as well as elemental analysis. The molecular structure of the metal complex trans-[Pt(p-tolyl3P)2(C≡CC6H4–p-NO2)2] (1) was confirmed by single crystal X-ray crystallography. The electronic absorption and photoluminescence spectra of the metal complexes and polymers have been used to probe their photophysical properties. The studies reveal that the presence of heavy metal atom and substituent groups on the phenyl ring of the ligands can enhance the efficiency of intersystem crossing from the S1 singlet excited state to the T1 triplet excited state and thus give intense phosphorescence." @default.
- W2077772916 created "2016-06-24" @default.
- W2077772916 creator A5006003842 @default.
- W2077772916 creator A5015870459 @default.
- W2077772916 creator A5017521861 @default.
- W2077772916 creator A5023497447 @default.
- W2077772916 creator A5047965868 @default.
- W2077772916 creator A5051954845 @default.
- W2077772916 creator A5057690903 @default.
- W2077772916 creator A5061163823 @default.
- W2077772916 creator A5063481044 @default.
- W2077772916 creator A5066769090 @default.
- W2077772916 creator A5067149311 @default.
- W2077772916 creator A5078062222 @default.
- W2077772916 date "2014-09-12" @default.
- W2077772916 modified "2023-09-26" @default.
- W2077772916 title "Synthesis, Structures and Properties of Novel Platinum(II) Acetylide Complexes and Polymers with Tri(tolyl)phosphine as the Auxiliary Ligand" @default.
- W2077772916 cites W141508194 @default.
- W2077772916 cites W1618644736 @default.
- W2077772916 cites W1668566020 @default.
- W2077772916 cites W1889723645 @default.
- W2077772916 cites W1963740321 @default.
- W2077772916 cites W1965420780 @default.
- W2077772916 cites W1968067088 @default.
- W2077772916 cites W1968253431 @default.
- W2077772916 cites W1969635440 @default.
- W2077772916 cites W1971984340 @default.
- W2077772916 cites W1979280980 @default.
- W2077772916 cites W1982779770 @default.
- W2077772916 cites W1983177597 @default.
- W2077772916 cites W1985137787 @default.
- W2077772916 cites W1987620130 @default.
- W2077772916 cites W1992384606 @default.
- W2077772916 cites W1995154656 @default.
- W2077772916 cites W2000144361 @default.
- W2077772916 cites W2001338086 @default.
- W2077772916 cites W2005286482 @default.
- W2077772916 cites W2006061867 @default.
- W2077772916 cites W2006967365 @default.
- W2077772916 cites W2007181486 @default.
- W2077772916 cites W2011685514 @default.
- W2077772916 cites W2012738419 @default.
- W2077772916 cites W2012912555 @default.
- W2077772916 cites W2012962061 @default.
- W2077772916 cites W2013440762 @default.
- W2077772916 cites W2013607539 @default.
- W2077772916 cites W2013830407 @default.
- W2077772916 cites W2014224202 @default.
- W2077772916 cites W2015437940 @default.
- W2077772916 cites W2015592584 @default.
- W2077772916 cites W2017702218 @default.
- W2077772916 cites W2020919619 @default.
- W2077772916 cites W2023336738 @default.
- W2077772916 cites W2023739445 @default.
- W2077772916 cites W2028165552 @default.
- W2077772916 cites W2030631054 @default.
- W2077772916 cites W2031476168 @default.
- W2077772916 cites W2031502808 @default.
- W2077772916 cites W2034010127 @default.
- W2077772916 cites W2042758277 @default.
- W2077772916 cites W2054084566 @default.
- W2077772916 cites W2057095635 @default.
- W2077772916 cites W2059020082 @default.
- W2077772916 cites W2060156889 @default.
- W2077772916 cites W2061447930 @default.
- W2077772916 cites W2062524885 @default.
- W2077772916 cites W2070157536 @default.
- W2077772916 cites W2070676933 @default.
- W2077772916 cites W2071947854 @default.
- W2077772916 cites W2072515914 @default.
- W2077772916 cites W2074688837 @default.
- W2077772916 cites W2082972359 @default.
- W2077772916 cites W2083588802 @default.
- W2077772916 cites W2088776569 @default.
- W2077772916 cites W2109215678 @default.
- W2077772916 cites W2114173368 @default.
- W2077772916 cites W2114239021 @default.
- W2077772916 cites W2131350133 @default.
- W2077772916 cites W2138679953 @default.
- W2077772916 cites W2150271653 @default.
- W2077772916 cites W2151793664 @default.
- W2077772916 cites W2152070739 @default.
- W2077772916 cites W2155990440 @default.
- W2077772916 cites W2161356509 @default.
- W2077772916 cites W2323245959 @default.
- W2077772916 cites W32310619 @default.
- W2077772916 cites W331825783 @default.
- W2077772916 doi "https://doi.org/10.1007/s10904-014-0071-7" @default.
- W2077772916 hasPublicationYear "2014" @default.
- W2077772916 type Work @default.
- W2077772916 sameAs 2077772916 @default.
- W2077772916 citedByCount "5" @default.
- W2077772916 countsByYear W20777729162015 @default.
- W2077772916 countsByYear W20777729162016 @default.
- W2077772916 countsByYear W20777729162017 @default.
- W2077772916 countsByYear W20777729162022 @default.
- W2077772916 crossrefType "journal-article" @default.
- W2077772916 hasAuthorship W2077772916A5006003842 @default.
- W2077772916 hasAuthorship W2077772916A5015870459 @default.
- W2077772916 hasAuthorship W2077772916A5017521861 @default.