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- W2077773920 startingPage "1097" @default.
- W2077773920 abstract "Rh(I) and Ir(I) cationic complexes [M(cod)(PP)]BF4 have been synthesised from diphosphite ligands 4–6 derived from ribofuranose. They have been used in the rhodium and iridium catalysed asymmetric hydrogenation of acrylic acid derivatives. Ribose derivative ligands 4–6 have also been used as auxiliaries in the Rh-catalysed hydroformylation of styrene. Hydroformylation results have been explained on the basis of the species formed under hydroformylation conditions. Comparative experiments with the related epimer d-(+)-xylose derivatives showed that the configuration of the product is controlled by the absolute configuration of the stereogenic carbon atom C-3." @default.
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- W2077773920 date "2000-03-01" @default.
- W2077773920 modified "2023-10-14" @default.
- W2077773920 title "Diphosphite ligands based on ribose backbone as suitable ligands in the hydrogenation and hydroformylation of prochiral olefins" @default.
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- W2077773920 doi "https://doi.org/10.1016/s0957-4166(00)00061-6" @default.
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