FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077797524> ?p ?o ?g. }

• W2077797524 endingPage "4578" @default.
• W2077797524 startingPage "4569" @default.
• W2077797524 abstract "Imido exchange of [TaCl3(NCMe3)(py)2] with 2-tert-butylaniline in refluxing benzene and crystallisation of the product from CH2Cl2 gave the anionic complex [Hpy][TaCl4(C6H4CMe3-2)(py)] 1. X-Ray structural analysis shows that with the Ta–N–C bond angle at 165.1(5)° two of the tert-butyl substituent methyl groups sit above two meridional chloro ligands but NMR spectroscopy indicates that the tert-butyl group can still rotate in solution. Reaction of isocyanates ArNCO [Ar = C10H7 (naphthyl), C6H4CMe3-2 or C6H4Ph-2] with WOCl4 in refluxing benzene gave [{WCl4(NC10H7)}x] 2, [{WCl4(NC6H4CMe3-2)}x] 3, and [{WCl4(NC6H4Ph-2)}x] 4 which NMR spectra show convert from two species into one in CDCl3. In refluxing toluene, 2-tert-butylphenyl isocyanate also forms the metallacyclic amido complex [WCl4{NHC6H4(CMe2CH2)-2(C,N)}] 5. The d1 complexes [WCl3(NC10H7)(PMe3)2] 6, [WCl3(NC6H4CMe3-2)(PMe3)2] 7, [WCl3(NC6H4Ph-2)(PMe3)2] 8, [WCl3(NC10H7)(PMe2Ph)2] 9 and [WCl3(NC10H7)(PMePh2)2] 10 were prepared, and show hindered imido ligand aryl C–N bond rotation. A crystal structure determination of 6 shows the naphthyl ring C-8 proton positioned between a chloro and phosphine ligand. Also prepared to demonstrate hindered aryl C–N bond rotation were the d2 complexes [WCl2(NC10H7)(PMe3)3] 11, [WCl2(NC6H4CMe3-2)(PMe3)3] 12, [WCl2(NC6H4Ph-2)(PMe3)3] 13 and [WCl2(NC10H7)(PMe2Ph)3] 14. Crystal stucture determinations show the tert-butyl group in 12 located above a chloro ligand and the phenyl group in 13 located between a chloro and phosphine ligand. They also show the methyl and isopropyl substituents in [MoCl2(NC6H3Me-2-Pri-6)2(dme)] 15 form an anti configuration and in [MoCl2(NC6H4CMe3-2)2(dme)] 16 a syn configuration is identified where the Mo–N–C bond angles are determined by steric effects and crystal packing forces." @default.
• W2077797524 created "2016-06-24" @default.
• W2077797524 creator A5018961453 @default.
• W2077797524 creator A5022838367 @default.
• W2077797524 creator A5077109181 @default.
• W2077797524 creator A5086697562 @default.
• W2077797524 date "2000-01-01" @default.
• W2077797524 modified "2023-10-14" @default.
• W2077797524 title "Regiospecific influences of phenyl ring substituents in monoimido complexes of tantalum and tungsten and bis imido complexes of molybdenum" @default.
• W2077797524 cites W1997035683 @default.
• W2077797524 cites W2015621961 @default.
• W2077797524 cites W2031009106 @default.
• W2077797524 cites W2046547327 @default.
• W2077797524 cites W2058077662 @default.
• W2077797524 cites W2062855747 @default.
• W2077797524 cites W2070647912 @default.
• W2077797524 cites W2144332006 @default.
• W2077797524 cites W2167590372 @default.
• W2077797524 cites W286513275 @default.
• W2077797524 cites W2951560384 @default.
• W2077797524 doi "https://doi.org/10.1039/b006420n" @default.
• W2077797524 hasPublicationYear "2000" @default.
• W2077797524 type Work @default.
• W2077797524 sameAs 2077797524 @default.
• W2077797524 citedByCount "11" @default.
• W2077797524 countsByYear W20777975242012 @default.
• W2077797524 countsByYear W20777975242015 @default.
• W2077797524 crossrefType "journal-article" @default.
• W2077797524 hasAuthorship W2077797524A5018961453 @default.
• W2077797524 hasAuthorship W2077797524A5022838367 @default.
• W2077797524 hasAuthorship W2077797524A5077109181 @default.
• W2077797524 hasAuthorship W2077797524A5086697562 @default.
• W2077797524 hasConcept C115624301 @default.
• W2077797524 hasConcept C116569031 @default.
• W2077797524 hasConcept C121332964 @default.
• W2077797524 hasConcept C1276947 @default.
• W2077797524 hasConcept C155647269 @default.
• W2077797524 hasConcept C155860418 @default.
• W2077797524 hasConcept C161790260 @default.
• W2077797524 hasConcept C170493617 @default.
• W2077797524 hasConcept C178790620 @default.
• W2077797524 hasConcept C185592680 @default.
• W2077797524 hasConcept C2777691172 @default.
• W2077797524 hasConcept C2777716191 @default.
• W2077797524 hasConcept C2778142098 @default.
• W2077797524 hasConcept C2778689049 @default.
• W2077797524 hasConcept C2778981380 @default.
• W2077797524 hasConcept C2779578285 @default.
• W2077797524 hasConcept C2780263894 @default.
• W2077797524 hasConcept C2780378348 @default.
• W2077797524 hasConcept C2780534471 @default.
• W2077797524 hasConcept C2781076698 @default.
• W2077797524 hasConcept C4839761 @default.
• W2077797524 hasConcept C549387045 @default.
• W2077797524 hasConcept C55493867 @default.
• W2077797524 hasConcept C67787023 @default.
• W2077797524 hasConcept C71240020 @default.
• W2077797524 hasConcept C8010536 @default.
• W2077797524 hasConceptScore W2077797524C115624301 @default.
• W2077797524 hasConceptScore W2077797524C116569031 @default.
• W2077797524 hasConceptScore W2077797524C121332964 @default.
• W2077797524 hasConceptScore W2077797524C1276947 @default.
• W2077797524 hasConceptScore W2077797524C155647269 @default.
• W2077797524 hasConceptScore W2077797524C155860418 @default.
• W2077797524 hasConceptScore W2077797524C161790260 @default.
• W2077797524 hasConceptScore W2077797524C170493617 @default.
• W2077797524 hasConceptScore W2077797524C178790620 @default.
• W2077797524 hasConceptScore W2077797524C185592680 @default.
• W2077797524 hasConceptScore W2077797524C2777691172 @default.
• W2077797524 hasConceptScore W2077797524C2777716191 @default.
• W2077797524 hasConceptScore W2077797524C2778142098 @default.
• W2077797524 hasConceptScore W2077797524C2778689049 @default.
• W2077797524 hasConceptScore W2077797524C2778981380 @default.
• W2077797524 hasConceptScore W2077797524C2779578285 @default.
• W2077797524 hasConceptScore W2077797524C2780263894 @default.
• W2077797524 hasConceptScore W2077797524C2780378348 @default.
• W2077797524 hasConceptScore W2077797524C2780534471 @default.
• W2077797524 hasConceptScore W2077797524C2781076698 @default.
• W2077797524 hasConceptScore W2077797524C4839761 @default.
• W2077797524 hasConceptScore W2077797524C549387045 @default.
• W2077797524 hasConceptScore W2077797524C55493867 @default.
• W2077797524 hasConceptScore W2077797524C67787023 @default.
• W2077797524 hasConceptScore W2077797524C71240020 @default.
• W2077797524 hasConceptScore W2077797524C8010536 @default.
• W2077797524 hasIssue "24" @default.
• W2077797524 hasLocation W20777975241 @default.
• W2077797524 hasOpenAccess W2077797524 @default.
• W2077797524 hasPrimaryLocation W20777975241 @default.
• W2077797524 hasRelatedWork W1546226164 @default.
• W2077797524 hasRelatedWork W1963650716 @default.
• W2077797524 hasRelatedWork W2012364498 @default.
• W2077797524 hasRelatedWork W2027866636 @default.
• W2077797524 hasRelatedWork W2030104769 @default.
• W2077797524 hasRelatedWork W2044330700 @default.
• W2077797524 hasRelatedWork W2070675310 @default.
• W2077797524 hasRelatedWork W2320681172 @default.
• W2077797524 hasRelatedWork W2344161753 @default.
• W2077797524 hasRelatedWork W4323284552 @default.

• next