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- W2077804910 abstract "Azafulvenium methides and diazafulvenium methides have been generated under microwave irradiation from 2,2-dioxo-1H,3H-pyrrolo[1,2-c]thiazoles and 2,2-dioxo-1H,3H-pyrazolo[1,5-c]thiazoles, respectively. Pericyclic reactions of these 1,7-dipole intermediates, namely, sigmatropic [1,8]H shifts, 1,7-electrocyclization or [8π+2π] cycloaddition led to the synthesis of a range of pyrrole and pyrazole derivatives. The first evidence for the azafulvenium methides by intermolecular trapping via [8π+2π] cycloaddition is reported." @default.
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- W2077804910 date "2008-08-01" @default.
- W2077804910 modified "2023-09-23" @default.
- W2077804910 title "Microwave-assisted generation and reactivity of aza- and diazafulvenium methides: heterocycles via pericyclic reactions" @default.
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- W2077804910 doi "https://doi.org/10.1016/j.tetlet.2008.06.013" @default.
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