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- W2077805613 abstract "Abstract Kerogen has been pyrolysed with additives (including minerals found in shale) under various flow rates (50–250 ml/min) of helium to sweep the product oil from the kerogen and mineral residues. For the product oil, carbon preference indexes for alkanes and alkenes, relative proportions of external and internal alkenic protons and carbon aromaticities were measured. The aromaticities of the pyrolysis residues were also measured and the fraction of aliphatic carbon converted to aromatic carbon during pyrolysis was calculated. The ratio of alkenes with external protons to alkenes with internal protons was altered by some of the additives and changes in the carbon preference indexes were also observed. Only charcoal and massive (10:1 kerogen) amounts of pyrite induced aromatisation. It is suggested that alkene and alkane formation during kerogen pyrolysis is independent of aromatisation and much of the aromatisation is due to the intrinsic structure or the kerogen and not to mineral matter effects." @default.
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- W2077805613 date "1993-04-01" @default.
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- W2077805613 title "Role of minerals and additives during kerogen pyrolysis" @default.
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- W2077805613 doi "https://doi.org/10.1016/0378-3820(93)90052-6" @default.
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