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• W2077805904 startingPage "1463" @default.
• W2077805904 abstract "Copper bromide promoted reactions of aldehydes, 1-alkynes, and chiral 2-dialkylaminomethylpyrrolidine at 25 °C give the corresponding chiral propargylamine derivatives in up to 96% yield and 99:1 dr that are readily converted to the corresponding disubstitued chiral allenes in up to 81% yield and 99% ee upon reaction with CuI in dioxane at 100 °C." @default.
• W2077805904 created "2016-06-24" @default.
• W2077805904 creator A5036599524 @default.
• W2077805904 creator A5084837140 @default.
• W2077805904 date "2013-02-04" @default.
• W2077805904 modified "2023-10-08" @default.
• W2077805904 title "Copper(I) Halide Promoted Diastereoselective Synthesis of Chiral Propargylamines and Chiral Allenes using 2-Dialkylaminomethylpyrrolidine, Aldehydes, and 1-Alkynes" @default.
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• W2077805904 doi "https://doi.org/10.1021/jo302534f" @default.
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