FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077809072> ?p ?o ?g. }

• W2077809072 endingPage "4544" @default.
• W2077809072 startingPage "4537" @default.
• W2077809072 abstract "The photocatalytic oxidation (PCO) of 2-propanol and acetone was studied on TiO2 powder at high coverage (>2 monolayers) at various oxygen concentrations using in situ FTIR. Two UV irradiation sources, either a continuous-wave UV lamp or an excimer laser, were applied to investigate the effect of the UV source on the PCO. It was found that higher oxygen concentrations increased the PCO rate of 2-propanol and acetone. The excimer laser source accelerated the PCO rate of 2-propanol while decelerating that of acetone as compared to the continuous-wave source. This effect was found to be larger at higher oxygen concentrations. Factors such as multiphoton adsorption or a pulsed irradiation were excluded as possible explanations for the irradiation source effect. More likely, the laser source changes the reaction mechanism by introducing an abrupt temperature increase, and hence the thermal decomposition, that is, dehydration of 2-propanol to propene, is effectively initiated on the surface. The PCO of 2-propanol was found to proceed along two routes: one was through the chemisorbed species, 2-propoxide, to form CO2 directly; the other was through conversion of H-bonded 2-propanol to acetone, followed by thermal fragmentation of mesityl oxide (aldol condensation product of acetone) to form formate species, and finally to CO2. It was also found that the acetone decay rate during acetone PCO was much faster than that of acetone formed as an intermediate during 2-propanol PCO at the same oxygen concentration. This was likely due to the presence of other species competing for reaction sites on the catalyst surface." @default.
• W2077809072 created "2016-06-24" @default.
• W2077809072 creator A5014714747 @default.
• W2077809072 creator A5023366064 @default.
• W2077809072 creator A5029553936 @default.
• W2077809072 date "2003-04-17" @default.
• W2077809072 modified "2023-09-26" @default.
• W2077809072 title "Effect of Irradiation Sources and Oxygen Concentration on the Photocatalytic Oxidation of 2-Propanol and Acetone Studied by in Situ FTIR" @default.
• W2077809072 cites W1513562284 @default.
• W2077809072 cites W1965641891 @default.
• W2077809072 cites W1973617158 @default.
• W2077809072 cites W1990249941 @default.
• W2077809072 cites W1990932273 @default.
• W2077809072 cites W1990962076 @default.
• W2077809072 cites W1991080490 @default.
• W2077809072 cites W1997524226 @default.
• W2077809072 cites W1999888753 @default.
• W2077809072 cites W2004925611 @default.
• W2077809072 cites W2005126580 @default.
• W2077809072 cites W2009762264 @default.
• W2077809072 cites W2022482476 @default.
• W2077809072 cites W2023643736 @default.
• W2077809072 cites W2024202513 @default.
• W2077809072 cites W2033118081 @default.
• W2077809072 cites W2055275269 @default.
• W2077809072 cites W2066651456 @default.
• W2077809072 cites W2067705313 @default.
• W2077809072 cites W2077845755 @default.
• W2077809072 cites W2079665803 @default.
• W2077809072 cites W2084462575 @default.
• W2077809072 cites W2110540540 @default.
• W2077809072 cites W2119585240 @default.
• W2077809072 cites W2148237394 @default.
• W2077809072 cites W293740587 @default.
• W2077809072 cites W4248309453 @default.
• W2077809072 doi "https://doi.org/10.1021/jp025995h" @default.
• W2077809072 hasPublicationYear "2003" @default.
• W2077809072 type Work @default.
• W2077809072 sameAs 2077809072 @default.
• W2077809072 citedByCount "81" @default.
• W2077809072 countsByYear W20778090722012 @default.
• W2077809072 countsByYear W20778090722013 @default.
• W2077809072 countsByYear W20778090722014 @default.
• W2077809072 countsByYear W20778090722015 @default.
• W2077809072 countsByYear W20778090722016 @default.
• W2077809072 countsByYear W20778090722017 @default.
• W2077809072 countsByYear W20778090722018 @default.
• W2077809072 countsByYear W20778090722019 @default.
• W2077809072 countsByYear W20778090722020 @default.
• W2077809072 countsByYear W20778090722021 @default.
• W2077809072 countsByYear W20778090722022 @default.
• W2077809072 countsByYear W20778090722023 @default.
• W2077809072 crossrefType "journal-article" @default.
• W2077809072 hasAuthorship W2077809072A5014714747 @default.
• W2077809072 hasAuthorship W2077809072A5023366064 @default.
• W2077809072 hasAuthorship W2077809072A5029553936 @default.
• W2077809072 hasConcept C111337013 @default.
• W2077809072 hasConcept C113196181 @default.
• W2077809072 hasConcept C121332964 @default.
• W2077809072 hasConcept C161790260 @default.
• W2077809072 hasConcept C178790620 @default.
• W2077809072 hasConcept C185544564 @default.
• W2077809072 hasConcept C185592680 @default.
• W2077809072 hasConcept C2778292535 @default.
• W2077809072 hasConcept C2779607525 @default.
• W2077809072 hasConcept C2781213060 @default.
• W2077809072 hasConcept C540031477 @default.
• W2077809072 hasConcept C65165184 @default.
• W2077809072 hasConcept C75473681 @default.
• W2077809072 hasConceptScore W2077809072C111337013 @default.
• W2077809072 hasConceptScore W2077809072C113196181 @default.
• W2077809072 hasConceptScore W2077809072C121332964 @default.
• W2077809072 hasConceptScore W2077809072C161790260 @default.
• W2077809072 hasConceptScore W2077809072C178790620 @default.
• W2077809072 hasConceptScore W2077809072C185544564 @default.
• W2077809072 hasConceptScore W2077809072C185592680 @default.
• W2077809072 hasConceptScore W2077809072C2778292535 @default.
• W2077809072 hasConceptScore W2077809072C2779607525 @default.
• W2077809072 hasConceptScore W2077809072C2781213060 @default.
• W2077809072 hasConceptScore W2077809072C540031477 @default.
• W2077809072 hasConceptScore W2077809072C65165184 @default.
• W2077809072 hasConceptScore W2077809072C75473681 @default.
• W2077809072 hasIssue "19" @default.
• W2077809072 hasLocation W20778090721 @default.
• W2077809072 hasOpenAccess W2077809072 @default.
• W2077809072 hasPrimaryLocation W20778090721 @default.
• W2077809072 hasRelatedWork W1985065027 @default.
• W2077809072 hasRelatedWork W1997595891 @default.
• W2077809072 hasRelatedWork W2008664702 @default.
• W2077809072 hasRelatedWork W2026719979 @default.
• W2077809072 hasRelatedWork W2082627234 @default.
• W2077809072 hasRelatedWork W2128471442 @default.
• W2077809072 hasRelatedWork W2137491005 @default.
• W2077809072 hasRelatedWork W2596585563 @default.
• W2077809072 hasRelatedWork W2768208640 @default.
• W2077809072 hasRelatedWork W2953328617 @default.
• W2077809072 hasVolume "107" @default.
• W2077809072 isParatext "false" @default.

• next