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- W2077819588 abstract "The design and preparation of stable cyanide-bearing six-coordinate complexes of formula [MIII(L)(CN)x](x + l − m)− (M = trivalent transition metal ion and L = polydentate blocking ligand) are summarized here. Their use as ligands towards either fully hydrated metal ions or coordinatively unsaturated preformed species, to afford a wide variety of low-dimensional metal assemblies whose nuclearity, dimensionality and magnetic properties can be tuned, is also reviewed. Special emphasis is put on the appropriate choice of the end-cap ligand L whose denticity determines the number of coordinated cyanide groups in the mononuclear precursors. Among the different new spin topologies obtained through this rational synthetic strategy, ferromagnetically coupled 4,2-ribbon like bimetallic chains which exhibit slow magnetic relaxation and hysteresis effects (chain as magnets) are one of the most appealing and constitute the heart of the present contribution." @default.
- W2077819588 created "2016-06-24" @default.
- W2077819588 creator A5018760070 @default.
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- W2077819588 date "2005-12-01" @default.
- W2077819588 modified "2023-10-17" @default.
- W2077819588 title "Design of single chain magnets through cyanide-bearing six-coordinate complexes" @default.
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