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• W2077828897 abstract "Pd(II) and Pt(II) complexes of [16]aneS4 and Pd(II) complexes of cis-(HO)2[14]aneS4 and [9]aneS3 have been used as templates for the self-assembly of polyiodide ions. The complexes {[M([16]aneS4)]2I}I11 (M = Pd, Pt), [Pd(cis-(HO)2[14]aneS4)](I3)2, [Pd([9]aneS3)2](Ix)2 (x = 3, 5) have been synthesized and structurally characterized. In {[M([16]aneS4)]2I}I11, the polyiodide network consists of fused 14-member polyanion rings made up of interacting “L”-shaped I5− and I− units; binuclear [([16]aneS4)M–I–M([16]aneS4)]3+ complex cations featuring a highly unusual linear and symmetric M–I–M moiety are each surrounded by one of these 14-member polyiodide rings in a belt-like fashion. The structures of [Pd(cis-(HO)2[14]aneS4)](I3)2 and [Pd([9]aneS3)2](I3)2 both feature tri-iodides as counter-anions. In [Pd(cis-(HO)2[14]aneS4)](I3)2, quite asymmetric I3− ions form sinusoidal infinite chains via head-to-tail I3−⋯I3− interactions; these chains run along the (001) direction and are stacked along the (100) direction to form highly puckered anionic layers via I⋯I weak interactions that cross-link the chains. In [Pd([9]aneS3)2](I3)2, [Pd([9]aneS3)2]2+ cations are bridged on each side by pairs of symmetric I3− ions through long-range S⋯I contacts to form discrete infinite ribbons that run parallel to the a axis. By contrast, the structure of [Pd([9]aneS3)2](I5)2 consists of highly puckered polyanionic layers featuring fused 18-member polyiodide rings made up of I5− ions. Two of these layers related by an inversion center are stacked along the b axis and interact with each other to form large cavities within which the complex cations sit. In these complex arrays the cation can be regarded as a template around which polyanion networks can be structured. The solid state FT-Raman spectra of the reported polyiodides are discussed on the basis of their crystal structures." @default.
• W2077828897 created "2016-06-24" @default.
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• W2077828897 date "1999-06-01" @default.
• W2077828897 modified "2023-10-10" @default.
• W2077828897 title "Thioether crown complexes as templates for the assembly of extended polyiodide networks: synthesis and structures of {[M([16]aneS4)]2I}I11 (M = Pd, Pt), [Pd(cis-HO)2[14]aneS4)](I3)2, [Pd([9]aneS3)2](Ix)2 (x = 3, 5)" @default.
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• W2077828897 doi "https://doi.org/10.1016/s1463-0184(99)00016-7" @default.
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