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- W2077829658 abstract "Propylene oxidation over a supported copper catalyst was studied by simultaneous measurements of the catalytic activity and the solid-state properties by means of a microthermogravimetric analyzer combined with a flow device. Initially adsorbed acrolein strongly retarded the consecutive oxidation of successively formed acrolein and allowed consistent stabilization of a copper-rich cuprous oxide state. The most active and stable solid phase for highly selective acrolein formation in the working state was the copper-rich cuprous oxide state such as Cu2.17O. The state was found to be determined by the balance between the proceeding of copper oxidation and the keeping in check of the oxidation by the retardation due to adsorbate." @default.
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- W2077829658 date "1980-09-01" @default.
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- W2077829658 title "Influence of retardation caused by partially oxidized adsorbate upon the oxidation state of copper catalyst and its performance for selective propylene oxidation" @default.
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- W2077829658 doi "https://doi.org/10.1016/0021-9517(80)90290-0" @default.
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