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• W2077832944 abstract "Abstract Differential thermal analysis, differential scanning calorimetry, and measurements of the 1 H spin-lattice relaxation times and second moments of 1 H-NMR absorptions were performed on methylammonium tetrachlorozincate (II) crystals over a wide temperature range. A solid-solid phase transition was located at 477 K. From the 1 H-NMR experiments it was found that the cations undergo overall reorientation as well as three dimensional translational self-diffusion in the high-temperature phase. In the low-temperature phase, a 120° reorientational motion of the CH 3 and NH 3 + groups of the cation about its C-N bond axis was detected. The parameters for the motional modes of the cations in the crystal were evaluated from the analysis of the 1 H-NMR experimental results." @default.
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• W2077832944 date "1989-08-01" @default.
• W2077832944 modified "2023-10-16" @default.
• W2077832944 title "Self-Diffusion and Reorientation of Methylammonium Ions in (CH₃NH₃)₂ZnCl₄ Crystals as Studied by ¹H-NMR" @default.
• W2077832944 doi "https://doi.org/10.1515/zna-1989-0811" @default.
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