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- W2077836100 abstract "Abstract The effects of phosphorus substituents on the reactivity of α‐alkoxyphosphonium salts with nucleophiles has been explored. Reactions of α‐alkoxyphosphonium salts, prepared from various acetals and tris( o ‐tolyl)phosphine, with a variety of nucleophiles proceeded efficiently. These processes represent the first examples of high‐yielding nucleophilic substitution reactions of α‐alkoxyphosphonium salts. The reactivity of these salts was determined by a balance between steric and electronic factors, respectively, represented by cone angles θ and CO stretching frequencies ν (steric and electronic parameters, respectively). In addition, a novel reaction of α‐alkoxyphosphonium salts derived from Ph 3 P with Grignard reagents was observed to take place in the presence of O 2 to afford alcohols in good yields. A radical mechanism is proposed for this process that has gained support from isotope‐labeling and radical‐inhibition experiments." @default.
- W2077836100 created "2016-06-24" @default.
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- W2077836100 date "2012-07-24" @default.
- W2077836100 modified "2023-10-18" @default.
- W2077836100 title "Effects of Phosphorus Substituents on Reactions of α-Alkoxyphosphonium Salts with Nucleophiles" @default.
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- W2077836100 doi "https://doi.org/10.1002/chem.201200480" @default.
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