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- W2077846095 abstract "A FEW examples of the occurrence of aromatization of alicyclic compounds in the animal body are known, and similar reactions have been suggested in the formation of sex hormones and possibly carcinogens from sterols and bile acids1. Hitherto, however, the reaction has not been demonstrated in isolated tissues. The ready conversion of cyclo hexane carboxylic acid to benzoic acid by the dog, man and rabbit2 suggested investigation of this transformation as a preliminary to the fuller study of aromatization in tissues. Rabbits of about 2.8 kgm. weight were first fed or injected subcutaneously with doses of 1.6–2.6 gm. sodium cyclo hexane carboxylate, of which about 0.9 gm. was isolated in the form of hippuric acid from the urine passed in the next 24 hours, thus confirming the work of Bernhard2, and showing an adequate rate of aromatization. A method was evolved3 for the micro-estimation of benzoic or hippuric acid in presence of cyclo hexane carboxylic acid, depending on cold nitration to the m-nitro derivative, reduction of the latter to the amino-compound, and estimation by diazotization and coupling with N-(l-naphthyl)-ethylene diamine." @default.
- W2077846095 created "2016-06-24" @default.
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- W2077846095 date "1947-06-01" @default.
- W2077846095 modified "2023-09-26" @default.
- W2077846095 title "Aromatization of cycloHexane Carboxylate in Liver Slices" @default.
- W2077846095 cites W2316376335 @default.
- W2077846095 doi "https://doi.org/10.1038/159839a0" @default.
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