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- W2077868650 abstract "Abstract The salts [CO(C 5 H 5 ) 2 ] + [Mn(CO) 5 ] − and [CR(C 6 H 6 ) 2 + [Mn(CO) 5 ] − show longwavelength absorptions at λ max 740 nm and 665 nm. These bands are assigned to metal to metal charge transfer (MMCT) transitions from Mn −I to Co III and Cr I . Upon MMCT excitation the former ion pair is converted to Co(C 5 H 5 ) 2 and Mn 2 (CO) 10 . The latter ion pair undergoes an analogous redox reaction as a thermal process. The thermal and the light-induced electron transfer are explained on the basis of the Hush model." @default.
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- W2077868650 date "1989-08-01" @default.
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- W2077868650 title "Photoredox reaction of cobalticinium pentacarbonylmanganate(−I) induced by outer-sphere metal to metal charge transfer excitation" @default.
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- W2077868650 doi "https://doi.org/10.1016/0022-328x(89)87240-7" @default.
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