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- W2077871919 abstract "The adsorption of dl-homocysteine (Hcy) and l-homocysteine thiolactone (HTL) on Au(1 1 1) electrode was investigated in 0.1 M HClO4 by cyclic voltammetry and in situ scanning tunneling microscopy (STM). Hcy and HTL molecules formed highly ordered adlayers on Au(1 1 1) surface. High-resolution STM images revealed the orientation and packing arrangement in the ordered adlayers. Hcy molecules formed (23×33)R30° adlayer structure and H-bonds between carboxyl groups were assumed to be responsible for the origin of tail-to-tail or head-to-head molecular arrangement, while HTL molecules formed (4×6) adlayer structure, and two different orientations and appearances in the ordered adlayer were found. Structural models were proposed for the two adlayers." @default.
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- W2077871919 date "2004-04-01" @default.
- W2077871919 modified "2023-10-18" @default.
- W2077871919 title "Adlayer structures of dl-homocysteine and l-homocysteine thiolactone on Au(1 1 1) surface: an in situ STM study" @default.
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- W2077871919 doi "https://doi.org/10.1016/j.electacta.2003.12.002" @default.
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