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- W2077874373 abstract "Abstract Highly boron-doped diamond electrodes are characterized voltammetrically employing Ru(NH 3 ) 6 3+/2+ , Fe(CN) 6 3−/4− , benzoquinone/hydroquinone, and cytochrome c redox systems. The diamond electrodes, which are polished to nanometer finish, are initially `activated' electrochemically and then pretreated by oxidation, reduction, or polishing. All electrodes give reversible cyclic voltammetric responses for the reduction of Ru(NH 3 ) 6 3+ in aqueous solution. Redox systems other than Ru(NH 3 ) 6 3+/2+ show characteristic electrochemical behavior as a function of diamond surface pretreatment. In particular, the horse heart cytochrome c redox system is shown to give reversible voltammetric responses at Al 2 O 3 polished boron-doped diamond electrodes. No voltammetric response for cytochrome c is detected at anodically pretreated diamond electrodes. The observations are attributed to preferential interaction of the polished diamond surface with the reactive region of the cytochrome c molecule and low interference due to a lack of protein electrode fouling." @default.
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- W2077874373 date "2002-01-01" @default.
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- W2077874373 title "Direct cytochrome c electrochemistry at boron-doped diamond electrodes" @default.
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- W2077874373 doi "https://doi.org/10.1016/s1388-2481(01)00272-7" @default.
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