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- W2077880057 abstract "An investigation has been carried out by 19F NMR on the Cd1−xBixF2+x solid solution which is a fast fluorine ion conductor. The results are interpreted on hand of the existence of different fluoride sublattices and exchanges between them at rising temperature. The diffusive character of the mobile F− ions motion is shown above T ⋍ 350 K. The NMR study has allowed to justify the hypothesis of the formation of clusters of 2:2:2 type in Cd1−xBixF2+x. Improvement with increasing x of the electrical conductivity above x ⋍ 0.05 may result mainly from the higher number of 2:2:2 clusters and consequently from that of the mobile anions." @default.
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- W2077880057 date "1991-08-01" @default.
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- W2077880057 title "Diffusion and clustering in the Cd1−xBixF2+x solid solution: A fluorine NMR study" @default.
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- W2077880057 doi "https://doi.org/10.1016/0022-4596(91)90321-8" @default.
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