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• W2077881242 abstract "The surface properties of ZrMn2 and TiMn2−x (x = 0, 0.5) were investigated using X-ray photoelectron spectroscopy because of the readiness of hydrogen sorption of many AB2 compounds. The concentration of the components and their chemical state were analysed in samples which had been fractured in an ultrahigh vacuum, exposed to increasing doses of oxygen and air and subjected to hydrogen absorption and desorption. It is concluded that surface segregation accounts for the ease with which hydrogen is absorbed. Manganese, but not zirconium or titanium, segregates and is preferentially oxidized. Zirconium and titanium are assumed to form metallic precipitates on the subsurface below the oxidized manganese. The precipitates and the subsurface can catalyse the H2  2H reaction. Furthermore the precipitates themselves may form hydrides and spill over atomic hydrogen to the intermetallic." @default.
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• W2077881242 date "1983-01-01" @default.
• W2077881242 modified "2023-09-25" @default.
• W2077881242 title "Surface properties of hydride-forming AB2 compounds" @default.
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• W2077881242 doi "https://doi.org/10.1016/0022-5088(83)90246-1" @default.
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