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• W2077884318 abstract "Siloxane-based polymers (polysiloxanes) exhibit a range of volume, viscosity, and pressure-viscosity behaviors that are strongly influenced by the macromolecular structure. In this report, a combination of extant rheological models is applied to develop a molecular-rheological modeling formalism that predicts polysiloxane rheological properties, such as specific volume, which means density, viscosity, and pressure-viscosity index variations with macromolecular structure, pressure, and temperature. Polysiloxane molecular features are described in terms of alkyl branch length L, pendant type J, density of branch functional monomers Q, and degree of polymerization DP. Both new and published data are used for model parameter determination and validation. Several siloxane-based polymers with alkyl, aryl, alkyl-aryl, cycloalkyl, and halogenated branches were synthesized to examine the modeled relationship between their molecular structures and rheological behaviors." @default.
• W2077884318 created "2016-06-24" @default.
• W2077884318 creator A5000731301 @default.
• W2077884318 creator A5010040085 @default.
• W2077884318 creator A5037078181 @default.
• W2077884318 creator A5046225712 @default.
• W2077884318 creator A5051920789 @default.
• W2077884318 date "2013-10-07" @default.
• W2077884318 modified "2023-09-27" @default.
• W2077884318 title "Modeling Polysiloxane Volume and Viscosity Variations With Molecular Structure and Thermodynamic State" @default.
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