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- W2077887213 abstract "The synthesis of short chain S-methyl thioesters was investigated in Geotrichum candidum strain GcG. The results indicated the involvement of an enzymatic reaction in this microorganism that led to the synthesis of S-methyl thioacetate (MTA) when methanethiol and acetyl-CoA were used as substrates. MTA was generated from these substrates by enzymatic or spontaneous reactions, whose relative importance depended largely on pH and temperature. For longer chain acyl-CoA compounds (C3 to C6), thioester synthesis was primarily spontaneous. Short chain fatty acid activation by a CoA residue probably is a prerequisite for the synthesis of S-methyl thioesters." @default.
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- W2077887213 date "2000-12-01" @default.
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- W2077887213 title "Enzymatic versus spontaneous<i>S</i>-methyl thioester synthesis in<i>Geotrichum candidum</i>" @default.
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- W2077887213 doi "https://doi.org/10.1111/j.1574-6968.2000.tb09430.x" @default.
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