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- W2077887544 abstract "High resolution photoelectron spectra are reported for styrene and stilbene with an emphasis on identifying the low frequency modes which are important in the phenyl–vinyl torsional motion. In the styrene cation three low frequency out-of-plane vibrations are measured, ν 42 , ν 41 and ν 40 as well as a number of higher frequency in plane modes. Generally the low frequency modes do not appear with significant intensity but by pumping the appropriate modes in the S 1 intermediate state the intensity for these modes in the threshold ionization spectrum is quite good. In the stilbene cation the analogous phenyl–vinyl torsion, ν 37 , is also measured as well as the related mode ν 36 . The ethylene torsional mode in stilbene is not observed. In both molecules the observed frequencies are used to relate the electronic structure of the cation to the S 1 and S 0 states of the molecule." @default.
- W2077887544 created "2016-06-24" @default.
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- W2077887544 date "1994-01-01" @default.
- W2077887544 modified "2023-10-16" @default.
- W2077887544 title "Threshold Ionization Spectroscopy of the Low Frequency Vibrational Modes of Styrene and Trans-Stilbene Cations" @default.
- W2077887544 doi "https://doi.org/10.1155/1994/26207" @default.
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