Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077887814> ?p ?o ?g. }
- W2077887814 endingPage "6127" @default.
- W2077887814 startingPage "6124" @default.
- W2077887814 abstract "Cellulose nanocrystals (CNCs), derived from cellulose, provide us with an opportunity to devise more sustainable solutions to current technological challenges. Enantioselective catalysis, especially heterogeneous, is the preferred method for the synthesis of pure chiral molecules in the fine chemical industries. Cellulose has been long sought as a chiral inducer in enantioselective catalysis. We report herein an unprecedentedly high enantiomeric excess (ee) for Pd patches deposited onto CNCs used as catalysts for the hydrogenation of prochiral ketones in water at room temperature and 4 bar H2. Our system, where CNCs acted as support and sole chiral source, achieved an ee of 65% with 100% conversions. Cryo-electron microscopy, high-resolution transmission electron microscopy, and tomography were used for the first time to study the 3D structure of a metal functionalized CNC hybrid. It established the presence of sub-nanometer-thick Pd patches at the surface of CNCs and provided insight into the chiral induction mechanism." @default.
- W2077887814 created "2016-06-24" @default.
- W2077887814 creator A5005309023 @default.
- W2077887814 creator A5007285706 @default.
- W2077887814 creator A5039913917 @default.
- W2077887814 creator A5068508198 @default.
- W2077887814 creator A5075286912 @default.
- W2077887814 creator A5088347763 @default.
- W2077887814 date "2015-05-05" @default.
- W2077887814 modified "2023-09-24" @default.
- W2077887814 title "Cellulose Nanocrystals as Chiral Inducers: Enantioselective Catalysis and Transmission Electron Microscopy 3D Characterization" @default.
- W2077887814 cites W1234070621 @default.
- W2077887814 cites W1969971371 @default.
- W2077887814 cites W1971916595 @default.
- W2077887814 cites W1976085475 @default.
- W2077887814 cites W1976533136 @default.
- W2077887814 cites W1977362012 @default.
- W2077887814 cites W1978068703 @default.
- W2077887814 cites W1979174951 @default.
- W2077887814 cites W1982041674 @default.
- W2077887814 cites W2001685666 @default.
- W2077887814 cites W2001728208 @default.
- W2077887814 cites W2004455143 @default.
- W2077887814 cites W2007246271 @default.
- W2077887814 cites W2010760005 @default.
- W2077887814 cites W2014042403 @default.
- W2077887814 cites W2015027122 @default.
- W2077887814 cites W2016049926 @default.
- W2077887814 cites W2023639591 @default.
- W2077887814 cites W2028063493 @default.
- W2077887814 cites W2041534175 @default.
- W2077887814 cites W2043210417 @default.
- W2077887814 cites W2050649040 @default.
- W2077887814 cites W2051265415 @default.
- W2077887814 cites W2057983092 @default.
- W2077887814 cites W2061329592 @default.
- W2077887814 cites W2066238972 @default.
- W2077887814 cites W2072748072 @default.
- W2077887814 cites W2082564222 @default.
- W2077887814 cites W2085817432 @default.
- W2077887814 cites W2088938002 @default.
- W2077887814 cites W2091218781 @default.
- W2077887814 cites W2091882134 @default.
- W2077887814 cites W2097616095 @default.
- W2077887814 cites W2099248508 @default.
- W2077887814 cites W2102515376 @default.
- W2077887814 cites W2109520483 @default.
- W2077887814 cites W2130949639 @default.
- W2077887814 cites W2141027215 @default.
- W2077887814 cites W2146393452 @default.
- W2077887814 cites W2166045210 @default.
- W2077887814 cites W2314799258 @default.
- W2077887814 cites W2315075984 @default.
- W2077887814 cites W2315470832 @default.
- W2077887814 cites W2316507136 @default.
- W2077887814 cites W2317855715 @default.
- W2077887814 cites W2319811501 @default.
- W2077887814 cites W2320403406 @default.
- W2077887814 cites W2332175292 @default.
- W2077887814 cites W2335605230 @default.
- W2077887814 cites W2477493984 @default.
- W2077887814 cites W2983666105 @default.
- W2077887814 cites W4210466733 @default.
- W2077887814 cites W4242517985 @default.
- W2077887814 cites W4245730967 @default.
- W2077887814 cites W4252718264 @default.
- W2077887814 cites W602730672 @default.
- W2077887814 doi "https://doi.org/10.1021/jacs.5b02034" @default.
- W2077887814 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25915443" @default.
- W2077887814 hasPublicationYear "2015" @default.
- W2077887814 type Work @default.
- W2077887814 sameAs 2077887814 @default.
- W2077887814 citedByCount "147" @default.
- W2077887814 countsByYear W20778878142015 @default.
- W2077887814 countsByYear W20778878142016 @default.
- W2077887814 countsByYear W20778878142017 @default.
- W2077887814 countsByYear W20778878142018 @default.
- W2077887814 countsByYear W20778878142019 @default.
- W2077887814 countsByYear W20778878142020 @default.
- W2077887814 countsByYear W20778878142021 @default.
- W2077887814 countsByYear W20778878142022 @default.
- W2077887814 countsByYear W20778878142023 @default.
- W2077887814 crossrefType "journal-article" @default.
- W2077887814 hasAuthorship W2077887814A5005309023 @default.
- W2077887814 hasAuthorship W2077887814A5007285706 @default.
- W2077887814 hasAuthorship W2077887814A5039913917 @default.
- W2077887814 hasAuthorship W2077887814A5068508198 @default.
- W2077887814 hasAuthorship W2077887814A5075286912 @default.
- W2077887814 hasAuthorship W2077887814A5088347763 @default.
- W2077887814 hasConcept C127413603 @default.
- W2077887814 hasConcept C146088050 @default.
- W2077887814 hasConcept C146686406 @default.
- W2077887814 hasConcept C161368742 @default.
- W2077887814 hasConcept C161790260 @default.
- W2077887814 hasConcept C171250308 @default.
- W2077887814 hasConcept C178790620 @default.
- W2077887814 hasConcept C185592680 @default.
- W2077887814 hasConcept C192562407 @default.