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- W2077890162 abstract "The structure of La 1/3 NbO 3 is that of a perovskite with La 3+ cations ordered into alternate layers of perovskite A -sites. This is the description of a tetragonal structure and yet the room-temperature structure shows an orthorhombic distortion. The structure of La 2/3 TiO 3 shows similar features. It has been recognized only very recently that the orthorhombic distortion in both these compounds is due to octahedral tilting. It seems clear from the literature that Ce 2/3 TiO 3 , Pr 2/3 TiO 3 , Nd 2/3 TiO 3 and Ce 1/3 NbO 3 adopt the same structure. Structures of other perovskites, such as Ln 2/3 TiO 3 , Ln 1/3 NbO 3 and Ln 1/3 TaO 3 (Ln = lanthanoid), when orthorhombically distorted, may be similar." @default.
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- W2077890162 date "2004-03-18" @default.
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- W2077890162 title "Structure for perovskites with layered ordering of <i>A</i>-site cations" @default.
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- W2077890162 doi "https://doi.org/10.1107/s0108768104003714" @default.
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