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- W2077898041 abstract "The triphenylphosphine (PPh3) displaces the acetonitrile from [PdCl2(CH3CN)2], and subsequent addition of the potassium cyanate causes substitution of the chloro ligand by NCO- to yield trans-[Pd(NCO)2(PPh3)2]. The complex was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The title compound was crystallized in a triclinic system, space group P1 with a = 9.213(3)Å, b = 9.781(7)Å, c = 10.483(5)Å, α = 111.39(5)°, β = 93.49(3)°, γ = 103.81(4)°, V = 845.0(1)Å3, Z = 1. The coordination geometry around Pd(II) in this complex is nearly square-planar, with the ligands in a trans relationship." @default.
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- W2077898041 date "2008-01-01" @default.
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- W2077898041 title "Molecular and Crystal Structure of trans-(Dicyanato)-bis(triphenylphosphine)palladium(II)" @default.
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- W2077898041 doi "https://doi.org/10.2116/analscix.24.x147" @default.
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