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- W2077907572 abstract "Treatment of 2-(2'-bromo-beta-phenethyl)isocarbostyrils 7 with AIBN-Bu(3)SnH in boiling benzene gave 8-oxoberbines 3 in good yields. A similar treatment of 2-(2'-bromo-beta-phenethyl)isoquinolinium bromides 6 and their nor- and homoanalogues (10,11) induced 6-, 5-, and 7-exo radical closures in a one-pot manner to give protoberberines 2, dibenzo[b,g]indolizidine 14a and, dibenzo[a, h]-1-azabicyclo[5.4.0]undecane 15a, respectively. A one-pot radical cyclization of 1-(2'-bromobenzyl)isoquinoline methiodide 18a gave a pavine alkaloid, (+/-)-algemonine (19a)." @default.
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- W2077907572 date "2000-07-06" @default.
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- W2077907572 title "Aryl Radical Cyclizations: One-Pot Syntheses of Protoberberine and Pavine Alkaloids" @default.
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- W2077907572 doi "https://doi.org/10.1021/ol006213a" @default.
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