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• W2077919776 endingPage "4867" @default.
• W2077919776 startingPage "4854" @default.
• W2077919776 abstract "The magnetism in ${mathrm{RbCoCl}}_{3}$ensuremath{cdot}${2mathrm{H}}_{2}$O (${T}_{N}$=2.97 K) is studied by high-temperature dynamic susceptibility and low-temperature electron-spin resonance. In order to describe the experiments a Hamiltonian is derived that includes spin-orbit coupling, tetragonal and rhombic distortions, exchange in the mean-field approximation, and an external magnetic field. A simultaneous fit to three mutual perpendicular susceptibilities yields consistent values for the crystal-field parameters and an intrachain exchange constant of J/${k}_{B}$=-5.0 K. The final Hamiltonian in the effective-spin s=(1/2) formalism is more or less of the planar type. The zero-field electron-spin-resonance spectra are described in terms of magnon bound states, i.e., the elementary excitations of the proposed Hamiltonian. The frequency independence and the angular dependence of both microwave and external fields are explained by the model. The temperature variations of the absorption intensity and linewidth are qualitatively discussed using simplified models." @default.
• W2077919776 created "2016-06-24" @default.
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• W2077919776 date "1986-04-01" @default.
• W2077919776 modified "2023-09-24" @default.
• W2077919776 title "Magnetism in the linear-chain antiferromagnetRbCoCl3⋅2H2O studied by dynamic susceptibility and electron-spin resonance" @default.
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• W2077919776 doi "https://doi.org/10.1103/physrevb.33.4854" @default.
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