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- W2077956749 abstract "The thione-to-thiol rearrangement rates for O-(2-alkenyl) (1a-c), O-(1-cyclopropylethyl) (1d) and O-(2-methylthioethyl) (1e) S-methyl xanthates were analyzed by the Kamlet-Taft equation. The results indicate that solvent polarity and solvent hydrogen-bond donation ability (acidity) are operative in the thione-to-thiol rearrangement reactions. In the case of 1e, the reaction is found to be influenced by solvent acidity and retarded by the increase of the solvent polarity." @default.
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- W2077956749 date "1998-07-01" @default.
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- W2077956749 title "Correlation of thione-to-thiol rearrangement rates of xanthates with solvent scales. Analysis of the reaction behavior by the Kamlet-Taft parameters, , α and β" @default.
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- W2077956749 doi "https://doi.org/10.1016/s0040-4020(98)00438-4" @default.
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