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- W2077964118 abstract "The solvent and rotational relaxation of Coumarin 153 (C-153) was investigated by picosecond time-resolved fluorescence spectroscopy in a room temperature ionic liquid (RTIL), 1-butyl-3-methylimidazolium octyl sulfate ([C4mim][C8SO4]). This is a typical RTIL, which form micellar structure above certain concentration of the RTIL (0.031 M). Dynamic light scattering (DLS) measurements show that the average hydrodynamic diameter (Dh) of a [C4mim][C8SO4]−water micelle is 2.8 (±0.2) nm. Both the solvent and rotational relaxation of C-153 are retarded in this micelle compared to the solvation time of a similar type of dye in neat water. However, the solvent relaxation in this ionic liquid surfactant is different from that of a conventional ionic surfactant. The slow component of the solvation dynamics in C8H17SO4Na or TX-100 micelle is on the nanoseconds time scale, whereas in [C4mim][C8SO4] micelle the same component is on the subnanoseconds time scale. The different molecular motions with different time scale is the main reason behind this difference in the solvation time in micelles composed of RTIL with other conventional micelles." @default.
- W2077964118 created "2016-06-24" @default.
- W2077964118 creator A5012579792 @default.
- W2077964118 creator A5042593602 @default.
- W2077964118 creator A5087308719 @default.
- W2077964118 date "2008-06-14" @default.
- W2077964118 modified "2023-09-25" @default.
- W2077964118 title "Dynamics of Solvent and Rotational Relaxation of Coumarin 153 in a Room Temperature Ionic Liquid, 1-Butyl-3-methylimidazolium Octyl Sulfate, Forming Micellar Structure" @default.
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- W2077964118 doi "https://doi.org/10.1021/la800813u" @default.
- W2077964118 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18553948" @default.
- W2077964118 hasPublicationYear "2008" @default.
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