FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077977145> ?p ?o ?g. }

• W2077977145 endingPage "101" @default.
• W2077977145 startingPage "93" @default.
• W2077977145 abstract "Di-tert-butyl nitroxide (DTBN) was adsorbed at several alkali metal ion exchanged Y zeolites to investigate the electron pair acceptor properties of the monovalent zeolite cations Li+, Na+, K+, and Cs+. This probe molecule forms adsorption complexes with the Lewis acidity possessing zeolite cations and thereby the spin density distribution at the nitroxide group of the DTBN molecule changes. This can directly be detected by electron spin resonance spectroscopy via the nitrogen hyperfine coupling constants of the probe molecule. A linear dependence of the nitrogen spin density at the π-orbital of the nitroxide group on the electronegativity of the zeolite cations was found. The Q values which relate the isotropic hyperfine structure coupling constant to the π-electron spin densities were determined. In comparison with these results, the nitrogen hyperfine coupling data of DTBN sorbed on the protonated form of the Y zeolite, possessing OH groups acting as Brøsnstedt acid sites, cannot be explained within this simple electronegativity model." @default.
• W2077977145 created "2016-06-24" @default.
• W2077977145 creator A5003285458 @default.
• W2077977145 creator A5009489291 @default.
• W2077977145 creator A5013043356 @default.
• W2077977145 creator A5034384811 @default.
• W2077977145 date "2001-09-01" @default.
• W2077977145 modified "2023-10-13" @default.
• W2077977145 title "Electron pair acceptor properties of alkali cations in zeolite Y: an electron spin resonance study of adsorbed di-tert-butyl nitroxide" @default.
• W2077977145 cites W1249811605 @default.
• W2077977145 cites W1965376178 @default.
• W2077977145 cites W1985918657 @default.
• W2077977145 cites W2002080608 @default.
• W2077977145 cites W2017581473 @default.
• W2077977145 cites W2024953760 @default.
• W2077977145 cites W2026254720 @default.
• W2077977145 cites W2042441723 @default.
• W2077977145 cites W2045163128 @default.
• W2077977145 cites W2049437228 @default.
• W2077977145 cites W2056811770 @default.
• W2077977145 cites W2065304986 @default.
• W2077977145 cites W2071164559 @default.
• W2077977145 cites W2073299501 @default.
• W2077977145 cites W2092523899 @default.
• W2077977145 cites W2093497711 @default.
• W2077977145 cites W2128057742 @default.
• W2077977145 cites W2134532152 @default.
• W2077977145 cites W2312528156 @default.
• W2077977145 cites W2316086634 @default.
• W2077977145 doi "https://doi.org/10.1016/s0927-7757(01)00605-7" @default.
• W2077977145 hasPublicationYear "2001" @default.
• W2077977145 type Work @default.
• W2077977145 sameAs 2077977145 @default.
• W2077977145 citedByCount "8" @default.
• W2077977145 countsByYear W20779771452012 @default.
• W2077977145 countsByYear W20779771452015 @default.
• W2077977145 crossrefType "journal-article" @default.
• W2077977145 hasAuthorship W2077977145A5003285458 @default.
• W2077977145 hasAuthorship W2077977145A5009489291 @default.
• W2077977145 hasAuthorship W2077977145A5013043356 @default.
• W2077977145 hasAuthorship W2077977145A5034384811 @default.
• W2077977145 hasConcept C111998727 @default.
• W2077977145 hasConcept C121332964 @default.
• W2077977145 hasConcept C131538251 @default.
• W2077977145 hasConcept C147789679 @default.
• W2077977145 hasConcept C15920480 @default.
• W2077977145 hasConcept C161790260 @default.
• W2077977145 hasConcept C169912494 @default.
• W2077977145 hasConcept C177293861 @default.
• W2077977145 hasConcept C178790620 @default.
• W2077977145 hasConcept C179104552 @default.
• W2077977145 hasConcept C184779094 @default.
• W2077977145 hasConcept C185592680 @default.
• W2077977145 hasConcept C187961010 @default.
• W2077977145 hasConcept C198091228 @default.
• W2077977145 hasConcept C2778077586 @default.
• W2077977145 hasConcept C2900893 @default.
• W2077977145 hasConcept C32909587 @default.
• W2077977145 hasConcept C46141821 @default.
• W2077977145 hasConcept C521977710 @default.
• W2077977145 hasConcept C75473681 @default.
• W2077977145 hasConcept C8010536 @default.
• W2077977145 hasConceptScore W2077977145C111998727 @default.
• W2077977145 hasConceptScore W2077977145C121332964 @default.
• W2077977145 hasConceptScore W2077977145C131538251 @default.
• W2077977145 hasConceptScore W2077977145C147789679 @default.
• W2077977145 hasConceptScore W2077977145C15920480 @default.
• W2077977145 hasConceptScore W2077977145C161790260 @default.
• W2077977145 hasConceptScore W2077977145C169912494 @default.
• W2077977145 hasConceptScore W2077977145C177293861 @default.
• W2077977145 hasConceptScore W2077977145C178790620 @default.
• W2077977145 hasConceptScore W2077977145C179104552 @default.
• W2077977145 hasConceptScore W2077977145C184779094 @default.
• W2077977145 hasConceptScore W2077977145C185592680 @default.
• W2077977145 hasConceptScore W2077977145C187961010 @default.
• W2077977145 hasConceptScore W2077977145C198091228 @default.
• W2077977145 hasConceptScore W2077977145C2778077586 @default.
• W2077977145 hasConceptScore W2077977145C2900893 @default.
• W2077977145 hasConceptScore W2077977145C32909587 @default.
• W2077977145 hasConceptScore W2077977145C46141821 @default.
• W2077977145 hasConceptScore W2077977145C521977710 @default.
• W2077977145 hasConceptScore W2077977145C75473681 @default.
• W2077977145 hasConceptScore W2077977145C8010536 @default.
• W2077977145 hasIssue "1-3" @default.
• W2077977145 hasLocation W20779771451 @default.
• W2077977145 hasOpenAccess W2077977145 @default.
• W2077977145 hasPrimaryLocation W20779771451 @default.
• W2077977145 hasRelatedWork W128347032 @default.
• W2077977145 hasRelatedWork W2003800782 @default.
• W2077977145 hasRelatedWork W2012522783 @default.
• W2077977145 hasRelatedWork W2033361932 @default.
• W2077977145 hasRelatedWork W2058564352 @default.
• W2077977145 hasRelatedWork W2064407762 @default.
• W2077977145 hasRelatedWork W2079315074 @default.
• W2077977145 hasRelatedWork W2292140352 @default.
• W2077977145 hasRelatedWork W2502069659 @default.
• W2077977145 hasRelatedWork W2950736751 @default.
• W2077977145 hasVolume "189" @default.

• next