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- W2077978049 abstract "The newly synthesized dinaphthyl propanes: 1,3-di-(2-naphthyl)-propane and 1-(1-naphthyl), 3-(2-naphthyl)-propane were studied spectroscopically under supersonic jet conditions and in solution. Under supersonic jet conditions, both molecules exhibit a broad, structureless fluorescence excitation spectrum and relatively short non-exponential decay of the highly red shifted fluorescence, consistent with strong interchromophore coupling in the excited state, resulting in, at least, partial excitation directly into an exciplex-like state. These observations are in contrast to the observed spectra and fluorescence decay of all other dinaphthalene bichromophoric molecules. Solution studies support these findings. The optimal flexible sandwich type geometry of both molecules is probably responsible for the observed exciplex state stabilization." @default.
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- W2077978049 date "2001-10-01" @default.
- W2077978049 modified "2023-10-16" @default.
- W2077978049 title "Solution and supersonic jet studies of the intramolecular exciplex of dinaphthyl propanes" @default.
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- W2077978049 doi "https://doi.org/10.1016/s1010-6030(01)00482-8" @default.
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