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• W2077978664 endingPage "105" @default.
• W2077978664 startingPage "101" @default.
• W2077978664 abstract "Abstract Metal phthalocyanine (MPc, M = Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ and Cu 2+ ), metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV–vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl 2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl 2 battery catalyzed by MPc is approximately 0–61% higher than that of Li/SOCl 2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl 2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl 2 battery in which SOCl 2 contains MPTpz is approximately 17–19% higher than that of the battery in the absence of compounds, and almost independent of central metal ions. It shows a correlation existing between the structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results." @default.
• W2077978664 created "2016-06-24" @default.
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• W2077978664 date "2010-03-01" @default.
• W2077978664 modified "2023-10-18" @default.
• W2077978664 title "Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery" @default.
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• W2077978664 doi "https://doi.org/10.1016/j.molcata.2009.11.014" @default.
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