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- W2077978930 abstract "In the present paper the mechanism of the γ-radiolysis of TANO and TEMPO in neutral deaerated aqueous solutions was investigated. The decomposition of TANO and TEMPO was followed spectrophotometrically by measuring the absorbance at the corresponding absorption maxima 235 and 245 nm. It was found, in agreement with other authors, that the main products of the radiolysis were the corresponding hydroxylamines TANOH and TEMPOH. In both cases a limiting decomposition yield was determined G(-TANO)=2.1, equal to GH+Ge-aq−12GOH and G(-TEMPO) =3.2, equal to GH+Ge-aq. TANO and TEMPO were also irradiated in aqueous solutions of n-C3H7OH, 2−C3H7OH, n−C4H9OH, CH3OH, C2H5OH and formic acid, where only reducing radicals were present. G(-TANO) and G(-TEMPO) were found to be ≈6.1, equal to GH+GOH+He−aq. The above results are consistent with the formation of the corresponding hydroxylamines, when nitroxyls react with H atoms, e-aq and hydroxyalkyl radicals. The EPR spectra of irradiated solutions suggest that OH radicals react with the nitroxyls by abstraction of H atoms, leading to the formation of biradicals." @default.
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- W2077978930 date "1981-01-01" @default.
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- W2077978930 title "Radiolysis of triacetoneaminoxyl (TANO) and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) in aqueous solutions" @default.
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- W2077978930 doi "https://doi.org/10.1016/0146-5724(81)90026-1" @default.
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