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- W2077987652 abstract "A detailed optical characterization by means of micro Raman and cathodoluminescence spectroscopy of catalyst-free ZnO nanorods grown by atmospheric-metal organic chemical vapour deposition has been carried out. This characterization has allowed correlating the growth conditions, in particular the precursors partial-pressures and growth time, with the optical properties of nanorods. It has been shown that a high Zn supersaturation can favor the incorporation of nonradiative recombination centers, which can tentatively be associated with ZnI-related defects. Characterization of individual nanorods has evidenced that ZnI-related defects have a tendency to accumulate in the tip part of the nanorods, which present dark cathodoluminescence contrast with respect to the nanorods bottom. The effect of a ZnO buffer layer on the properties of the nanorods has been also investigated, showing that the buffer layer improves the luminescence efficiency of the ZnO nanorods, revealing a significant reduction of the concentration of nonradiative recombination centers." @default.
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- W2077987652 date "2013-04-12" @default.
- W2077987652 modified "2023-10-15" @default.
- W2077987652 title "Influence of metal organic chemical vapour deposition growth conditions on vibrational and luminescent properties of ZnO nanorods" @default.
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- W2077987652 doi "https://doi.org/10.1063/1.4801534" @default.
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