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- W2077994597 abstract "Unimolecular fragmentation of the MH+ ions of a number of methionine derivatives such as H-Met-OMe, H-Met-β-naphthylamide, H-Met-Gly-OH, H-Met-Ala-OH and H-Met-Phe-OH results in formation of the methionine b1 ion (m/z 132) in significant yields. Since α-aminoacylium ions are generally unstable and not observed, it is proposed that the stable form of the b1 ion from these methionine derivatives is methyl-cationated α-amino-γ-thiobutyrolactone. Under low-energy collision-induced dissociation conditions this b1 ion readily loses CO to form the a1 ion, CH3SCH2CH2CH=NH2+. © 1998 John Wiley & Sons, Ltd." @default.
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- W2077994597 date "1998-07-15" @default.
- W2077994597 modified "2023-10-01" @default.
- W2077994597 title "The b1 ion derived from methionine is a stable species" @default.
- W2077994597 doi "https://doi.org/10.1002/(sici)1097-0231(19980715)12:13<849::aid-rcm237>3.0.co;2-w" @default.
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