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- W2077996210 abstract "The crystal structure determination of the title compound (abbreviated as α-LiPt(mnt) has been performed at room temperature and 153 K. The [Pt(mnt)2]n− (mnt=1,2-dicyano-1,2-ethylenedithiolato, C4N2S22−) anions stack face-to-face along the c-axis with Pt···Pt distance of 3.6 A. The room temperature structure and the average structure of the 153 K superstructure are almost the same. The room temperature conductivity of α-LiPt(mnt) is about 200 S cm−1, and the compound undergoes a metal-insulator transition (Peierls transition) at 220 K. In α-LiPt(mnt) the conduction pathway is through the ligand-centered π-system which is composed of predominantly S 3pz orbitals. Oscillation photographs about the c-axis show strong satellite spots on the layerlines of (0.41+n)c* and (0.59+n)c* (n=0, ±1, ±2, ···) The content of Li cation reveals that these satellite spots can be described as 2kF spots. The regular appearance of characteristic satellite reflections indicates that α-LiPt(mnt) has a sinusoidally modulated latt..." @default.
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- W2077996210 date "1984-11-01" @default.
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- W2077996210 title "Peierls Structure of (H<sub>3</sub>O)<sub>0.33</sub>Li<sub>0.8</sub>[Pt(mnt)<sub>2</sub>]·1.67H<sub>2</sub>O" @default.
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- W2077996210 doi "https://doi.org/10.1246/bcsj.57.3262" @default.
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