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- W2078004178 abstract "A porous metal organic framework [Ni III Ni II 2 ( μ 3 -OH)(bdc) 1.5 (int) 3 ] n x(solvents) ( 1 : bdc = 1,4-benzenedicarboxylate; int = isonicotinate) based on the trinuclear Ni 3 ( μ 3 -OH) units was solvothermally synthesized and structurally characterized. It features a three-dimensional 9-connected ncb -type framework with two kinds of cage substructures and large one-dimensional channels. Both N 2 and CO 2 gas sorption studies of 1 were investigated to demonstrate the permanent porosity in 1 . A microporous metal organic framework with 9-connected ncb topology is constructed from the trinuclear Ni 3 ( μ 3 -OH) units and shows gas sorption properties. ► Synthesis and structure of a microporous [Ni 3 (μ 3 -OH)] cluster-based framework ► Nine-connected ncb topology in metal organic framework ► A microporous metal organic framework with N 2 and CO 2 gas sorption properties" @default.
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- W2078004178 date "2011-10-01" @default.
- W2078004178 modified "2023-09-25" @default.
- W2078004178 title "A microporous [Ni3(μ3-OH)] cluster-based framework with 9-connected ncb topology" @default.
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- W2078004178 doi "https://doi.org/10.1016/j.inoche.2011.06.009" @default.
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