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- W2078005989 abstract "Abstract This article discusses polynuclear metal complexes of Schiff base macrocycles and their potential application to the modelling of metallobiosites, in particular di- and tri-nuclear copper(II)-containing sites. A brief perspective of the area is presented and then the article addresses the development of pyridinyl-derived bibracchial (doubly pendant-armed) Schiff base macrocycles and their metal complexes. The cleft-like configurations of the complexes bear resemblance to the metal-containing pockets present in metalloproteins. A ‘first generation’ model for the trinuclear copper site in ascorbate oxidase, and a dinuclear manganese(II) complex bearing a single acetato-bridge, and which may have relevance to the modelling of dinuclear manganese biosites, are discussed. An extension of the work to thiophene-derived macrocycles and their dicopper(I) complexes is also presented." @default.
- W2078005989 created "2016-06-24" @default.
- W2078005989 creator A5007276134 @default.
- W2078005989 creator A5037308279 @default.
- W2078005989 date "2010-08-04" @default.
- W2078005989 modified "2023-09-25" @default.
- W2078005989 title "ChemInform Abstract: Metal Complexes of Bibracchial Schiff Base Macrocycles" @default.
- W2078005989 cites W2952345937 @default.
- W2078005989 doi "https://doi.org/10.1002/chin.199638256" @default.
- W2078005989 hasPublicationYear "2010" @default.
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