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- W2078019144 abstract "The synthesis and characterization of the new ligand 4′-ferrocenylterpyridine is reported together with the synthesis and characterization of a new C3-ferrocenophane containing three acylpyridine units. The terpyridine ligand was prepared in a two-step synthesis from ferrocenecarbaldehyde by aldol condensation and subsequent cyclization. Attempts to prepare the analogous 1,1′-bis-terpyridylferrocene derivative resulted in the formation of a new ferrocenophane : a consequence of inter-annular attack of an anion generated on the side chain of one cyclopentadienyl ring on a carbonyl centre on the side chain of the other cyclopentadienyl ring. The single crystal X-ray structure of this ferrocenophane, [(η-C5H4CHCH2C(O)2-C5H4N)2CHC(O)2-C5H4N]Fe, as its dichloromethane solvate, [Fe(C33H27N3O3)] · CH2Cl2, has been determined." @default.
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- W2078019144 date "1995-02-01" @default.
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- W2078019144 title "Ferrocenylpyridines: a new synthesis of 4′-ferrocenylterpyridine and the single crystal structure of a C3-ferrocenophane, [(η-C5H4CHCH2C(O)2-C5H4N)2CHC(O)2-C5H4N]Fe" @default.
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- W2078019144 doi "https://doi.org/10.1016/0277-5387(94)00266-h" @default.
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