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- W2078019211 abstract "The gold(I)-catalyzed cycloisomerization of enynes containing an embedded cyclopropane unit leads selectively to the formation of ring systems containing the cyclopropylmethyl cation. A subsequent Wagner-Merwein shift provides diastereomerically pure fused cyclobutanes. The utility of this methodology for the rapid assembly of polycyclic ring systems is illustrated by the total synthesis of the angular triquinane ventricosene." @default.
- W2078019211 created "2016-06-24" @default.
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- W2078019211 date "2008-08-30" @default.
- W2078019211 modified "2023-10-01" @default.
- W2078019211 title "Au(I)-Catalyzed Ring Expanding Cycloisomerizations: Total Synthesis of Ventricosene" @default.
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- W2078019211 doi "https://doi.org/10.1021/ol801760w" @default.
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